气液螺旋环状流压降特性研究

考虑旋流衰减的影响，对气液螺旋环状流的压降特性进行研究并推导出了螺旋环状流压降预测模型。定义压降旋-直比系数为气液两相螺旋环状流和气液两相直流的压降之比，以此来表征旋流衰减对压降的影响。基于量纲分析的方法对压降旋-直比系数进行分析，推导出其表达式，压降旋-直比系数依赖于Lockhart-Martinelli 参数和气相Froude数变化。最终，得出了气液两相螺旋环状流的压降预测模型。在50 mm内径的水平管内对螺旋环状流的压降特性进行了实验研究，其中气相表观流速变化范围为10~16 m/s，体积含液率（LVF）变化范围为0.6%~4.8%。通过与实验数据进行对比，压降预测模型的相对误差在±15%以内，为工程应用提供了参考。     

注采比对“二三结合”开发模式渗流特征的影响

大庆油田的开发逐渐进入高含水阶段,厚油层动用程度低,"二三结合"开发模式是有效的提高厚油层动用程度,改善水驱开发效果,提高油田采收率的有效手段。在"二三结合"开发模式注聚阶段中注采比对井间压力、含水饱和度等变化有重要影响。为了探究注采比对开发层位的井间压力及饱和度的影响,利用油藏数值模拟方法,模拟了相同的开发模式不同注采比的生产情况,绘制了不同注采比情况下,不同层位的井间压力及含水饱和度变化情况,为维持地层压力平衡,保持油田稳定生产提供有力的依据。     

Study of metal assisted anisotropic chemical etching of silicon for high aspect ratio in crystalline silicon solar cells

Textured surface is commonly used to enhance the efficiency of silicon solar cells by reducing the overall reflectance and improving the light scattering. In this study, a comparison between isotropic and anisotropic etching methods was investigated. The deep funnel shaped structures with high aspect ratio are proposed for better light trapping with low reflectance in crystalline silicon solar cells. The anisotropic metal assisted chemical etching (MACE) was used to form the funnel shaped structures with various aspect ratios. The funnel shaped structures showed an average reflectance of 14.75% while it was 15.77% for the pillar shaped structures. The average reflectance was further reduced to 9.49% using deep funnel shaped structures with an aspect ratio of 1:1.18. The deep funnel shaped structures with high aspect ratios can be employed for high performance of crystalline silicon solar cells.     

全尾砂和废石联合胶结充填体最佳配比及应用

针对红岭铅锌矿分级充填骨料来源不足、地表废石堆积污染环境的情况,提出将该矿选厂产生的全尾砂和地表废石作为充填骨料的联合胶结充填方案。分别测试了全尾砂和地表废石的物理化学性质,验证了碎石和全尾砂作为联合充填骨料的可行性。通过充填配比试验,分析了不同配比全尾砂废石充填体强度特性,得出了最佳充填配比。结果表明,充填试块的强度随灰砂比减小而减小,随养护龄期增加呈增大趋势,随充填料浆质量浓度增大而增大,最佳配比为: 胶结充填灰砂比1∶8、普通充填灰砂比1∶12,全尾砂∶废石配比4∶6,质量浓度78%。根据研究结果,在红岭铅锌矿进行了全尾砂废石充填技术工业应用,证实该技术可行。     

Liquid yield from juniper and mesquite bio‐fuel gasification

Mesquite (Prosopis glandulosa) and redberry juniper (Juniperus pinchotii) are two woody species which dominate uncultivated lands in the south central Great Plains, USA (Texas, Oklahoma) and may have potential for bioenergy utilization. In this study, these two biomasses were gasified in an adiabatic, updraft fixed‐bed gasifier using air as medium. The products include low heating value gas and liquid tar yield. The effects of fuel moisture content and the equivalence ratio (ER) on liquid yields including heavy tar and light tar and higher heating value (HHV) of the producer gas were investigated. It was found that updraft gasifiers produce a large amount of tar, in a range of 100 g/Nm³ of gas produced. As the equivalence ratio (ER) increased (i.e. more rich char conditions), peak temperature (T_peak) within the bed decreased due to the lesser partial oxidization. The liquid yield showed peak value with change in moisture content between 6 and 24%. Heavy tar is a very high quality fuel with a higher heating value of over 29 MJ/kg on a dry, ash‐free (DAF) basis which is a slightly higher than that of ethanol. Copyright © 2015 John Wiley & Sons, Ltd.     

球化率及碳化物形貌对C35E钢精冲质量的影响

通过不同的球化退火工艺获得了不同球化率及碳化物形貌的C35E钢,研究了球化率和碳化物形貌对其精冲质量的影响。C35E钢的最佳球化退火保温温度为720,适当的温度下延长保温时间有助于提高其球化率。球化率越高,碳化物呈细小均匀分布,精冲件的冲裁质量越好。对于球化完全但碳化物呈团块状或带状分布的材料,其冲裁面上依然会出现断裂带。     

Combination of nuclear magnetic resonance spectroscopy and nonlinear methods to analyze the copolymerization of phosphonic acid derivatives

We demonstrate in this study that the combination of modern inline monitoring methods [here: inline nuclear magnetic resonance (NMR)] with simulations gains more exact and profound kinetic results than previously used methods like linearization without that combination. The ¹H-NMR spectroscopic data (more than 100 data points) are used to construct the copolymerization diagram. The reactivity ratios are obtained applying the van Herks nonlinear least square method. The examination of the radical copolymerization of 2-hydroxyethyl methacrylate (HEMA) with (2-{[2-(ethoxycarbonyl)prop-2-en-1-yl]oxy}ethyl) phosphonic acid (ECPPA) as important adhesive monomer used in dentistry yields reactivity ratios of r_HEMA = 1.83; r_ECPPA = 0.42. The copolymerization diagram reflects nonideal, non-azeotropic copolymerization. The sequence distribution of the obtained by Monte Carlo simulation indicates the generation of statistical copolymers. As an important finding, it is demonstrated that the repeating units responsible for etching and adhesion are arranged over the whole polymer chain, which is necessary to achieve proper functionality. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48256.     

基于多级混合澄清槽的PUREX流程的计算模型

主要通过建立分配比模型、化学反应模型、传质模型构建了一套基于混合澄清槽的PUREX流程中关键循环过程的计算模型（mathematical model for main PUREX process based on mixer-settler，简称MPMS），用于计算各级单元的物料浓度。通过检验两组具有代表性的PUREX工艺流程，模拟结果较好地匹配实验数据，表明该计算模型具有良好的精确性。该计算模型将为基于多级混合澄清槽的PUREX流程模拟提供有益帮助。